For that reason I'm thinking Pathfinder Witch. For hexes consider, Feral Speech, Healing and of course Prehensile Hair. The familiar also fits nicely. Actually had a character in a group once who went in that direction and the player did realize the similarities. There was a lot of hair-induced healing
Alternatively, the White-Haired Witch archetype ditches hexes in favor of doing ALL the hair stuff and a couple rogue talents. Not exactly a good trade, but maybe worth it for the concept alone.
This does of course assume that Pathfinder content is allowed.