This one is up to the DM's discretion as he's the one delegating how many free actions of a certain kind you can do at any given time. There's a good chance he'll say no.
Actually you can use any scroll of the correct type (arcane or divine) assuming the spell is on your spell list. So a magus could cast a scroll of shocking grasp that was scribed by a wizard. If the spell is not on your spell list, if your ability isn't high enough, or if the scroll is not of the right type, you are required to make a UMD check.