Bozzok, the Archfiends, Malack and the vampire Exarch come to mind.
Durkon* had his own agenda (kill Roy and make the dwarves pay) beyond Hel's was the main antagonist to be defeated gfor a significant portion of the book, so yes.
Edit: Also I should probably answer the question: For now my vote would be Durkon* he was clever, by far the most closely linked to a member of the Order and his defeat and whole concept was excellent and very well executed.
However, Redcloak and Xykon aren't far behind and their story isn't over yet so I am liable to change my mind.
Also, are we counting side-books villains?