Here,
From dictionary.com:
op·ti·mize
1. to make as effective, perfect, or useful as possible.
Now possible is the deal breaker here. Some people define possible as whatever is possible within the rules, which if you take that extreme pun pun can be your next new character. Some people define possible as whatever falls within their character concept. Both are fine definitions for possible.
And I'm not talking about powergaming, I'm talking about optimizing, there's a big difference.