I doubt it, but that depends on what the DMs say and what RAW says. RAW, you expend two spell slots of X level to cast a spell of X+1 level that you know. Runestaffs allow you to expend one slot of a spell level equal or higher than the spell you intend to cast. You aren't considered to know those spells, hence you can't use your Versatile Spellcaster-granted "spell slot" to cast a spell from a runestaff.
But, that's just me.