No, it doesn't, just PrCs.

Stick to Evil Spells, Feats, and Prestige Classes; you have some good options out there. For Base Classes, your only real choices are like, Paladin of Tyranny/Slaughter, LE or CE Soulborn, NE Incarnate, and... I think that's about it (and only one of those classes, the Incarnate, is any good at all). I mean, Evil Clerics and Crusaders get a few abilities that are different from their Neutral counterparts, but that's minor.

So yeah, take some nice Evil feats or spells, and prepare yourself for an evil PrC or two, and play the character as Evil, and you should be doing alright. I get that you want to take advantage of the opportunity, but base classes just don't really give you that option.